Research in the Radiochemistry Program includes coordination chemistry, speciation, separations, spectroscopy, heavy element chemistry, and radioelement materials.  Publications by year from group members are below.

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2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016

Publications from 2016
Authors Reference
Denden, I.; Roques, J.; Poineau, F., Solari, P. L.; Schlegel. M.; Blain, G.; Fattahi, M.

Behavior of heptavalent technetium in concentrated triflic acid under alpha-irradiation: technetium-triflate complex characterized by X-ray absorption fine structure spectroscopy and DFT. Radiochim. Acta, (2016), accepted for publication.

Poineau, F., Koury, D. K.; Bertoia, J.; Kolman. D. G.; Mausolf, E.J.; Goff, G. S; Kim, E.; Jarvinien, G. D.; German, K. E.; Czerwinski, K. R

Electrochemical studies of technetium-ruthenium alloys in HNO3: implications for the behavior of technetium waste forms. Radiochemistry (2016), accepted for publication.

Childs, B. C.; Braband, H.; Lawler, K.; Mast, D. S.; Bigler, L.; Urs, S.; Forster, P. M.; Czerwinski, K. R.; Alberto, R.; Sattelberger, A. P.; Poineau, F. Ditechnetium heptoxide revisited: solid-state, gas-phase and first principle studies. Inorg. Chem. (2016), DOI: 10.1021/acs.inorgchem.6b01683, in press.
Poineau, F.; Mausolf, E. J.; Kerlin, W.; Czerwinski, K. R. Hexaammine-cobalt(III) pertechnetate : preparation, structure and solubility J. Radioanal. Nucl. Ch. (2016), accepted for publication, DOI :10.1007/s10967-016-5052-6, in press.
Burton-Pye, B. P.; Poineau, F.; Bertoia, J.; Czerwinski, K. R.; Francesconi, L. C.; Sattelberger, A. P.

Photochemical behavior of the quadruply metal-metal bonded [Tc2Cl8]2- anion in acetonitrile. Inorg. Chim. Acta (2016)DOI: 10.1016/j.ica.2016.09.041, in press.

Mariappan Balasekaran, E.; Todorova, T. K.; Pham, C. T.; Hartmann, T.; Abram, U.; Sattelberger, A. P.; Poineau, F.

Molecular and electronic structure of Re2Br4(PMe3)​4. Inorg. Chem. (2016), 55, 5417-5421.

Johnstone, E. V.; Poineau, F.; Todorova, T. K.; Forster, P. M.; Soerensen, L. K.; Fdez Galvan, I.; Lindh, R.; Czerwinski, K. R.; Sattelberger, A. P.

Octafluorodirhenate(III) revisited: solid-​state preparation, characterization, and multiconfigurational quantum chemical calculations. Inorg. Chem. (2016), 55, 7111-7116.

Poineau, F; Silva, C.; Yeamans, C. B.; Cerefice, G. S.; Sattelberger, A. P.; Czerwinski, K. R.

Structural study of the ammonium octafluoroneptunate, [NH4]​4NpF8. Inorg. Chim. Acta (2016), 448, 93-96.

Riddle, C.; Czerwinski, K.; Kim, E.; Paviet, P.; Weck, P.; Poineau, F.; Conradson, S.

Characterization of pentavalent and hexavalent americium complexes in nitric acid using X-​ray absorption fine structure spectroscopy and first-​principles modeling. J. Radioanal. Nucl. Ch. (2016), 309, 1087-1095.

Mast, D. S.; Kim, E.; Siska, E. M.; Poineau, F.; Czerwinski, K. R.; Lavina, B.; Forster, P. M. Equation of state for technetium from X-​ray diffraction and first-​principle calculations. J. Phys. Chem. Solids (2016), 95, 6-11.
Publications from 2015
Authors Reference
Poineau, F.; German, K. E.; Burton-Pye, B. P.; Weck, P. F.; Kim, E.; Kriyzhovets, O.; Safonov, A.; Ilin, V.; Francesconi, L. C.; Sattelberger, A. P.; et al. Speciation of technetium peroxo complexes in sulfuric acid revisited. J. Radioanal. Nucl. Ch. (2015), 303, 1163-1167.
Childs, B. C.; Poineau, F.; Czerwinski, K. R.; Sattelberger, A. P. The nature of the volatile technetium species formed during vitrification of borosilicate glass. J. Radioanal. Nucl. Ch. (2015). 306(2), 417-421
Kerlin, W. M.; Poineau, F.; Forster, M.; Czerwinski, K. R.; Sattelberger, A. P.

Hydrothermal synthesis and solid-​state structures of polynuclear technetium iodide compounds. Inorg. Chim. Acta (2015), 424, 329-335.

Publications from 2014
Authors Reference
Poineau, F.; Johnstone, E. V.; Czerwinski, K. R.; Sattelberger, A. P.

Recent advances in technetium halide chemistry. Acc. Chem. Res. (2014), 47, 624-632.

Poineau, F.; Johnstone, E. V.; Czerwinski, K. R.

Bis(tetrabutylammonium) octachloroditechnetate(III). Inorganic Syntheses (2014), 36, 110-114.

Poineau, F.; Forster, P. M.; Todorova, T. K.; Johnstone, E. V.; Kerlin, W. M.; Gagliardi, L.; Czerwinski, K. R.; Sattelberger, A. P.

A decade of dinuclear technetium complexes with multiple metal-​metal bonds. Eur. J. Inorg. Chem. (2014), 2014, 4484-4495.

Ferrier, M.; Roques, J.; Poineau, F.; Sattelberger, A. P.; Unger, J.; Czerwinski, K. R.

Speciation of technetium in sulfuric acid​/hydrogen sulfide solutions. Eur. J. Inorg. Chem. (2014), 2014, 2046-2052.

Todorova, T. K.; Poineau, F.; Forster, P. M.; Gagliardi, L.; Czerwinski, K. R.; Sattelberger, A. P.

Molecular and electronic structure of Tc2(O2CCH3)​2Cl4 studied by multiconfigurational quantum chemical methods. Polyhedron (2014), 70, 144-147.

Habel-Rodriguez, D.; Poineau, F.; Johnstone, E. V.; Czerwinski, K. R.; Sattelberger, A. P.; Kirk, M. L.

Magnetic circular dichroism and electronic structure of [Re2X4(PMe3)​4]​+ (X = Cl, Br). Inorg. Chem. (2014), 53, 1260-1262.

Denden, I.; Poineau, F.; Schlegel, M. L.; Roques, J.; Solari, P. Lorenzo; Blain, G.; Czerwinski, K. R.; Essehli, R.; Barbet, J.; Fattahi, M.

Behavior of heptavalent technetium in sulfuric acid under α-​irradiation: structural determination of technetium sulfate complexes by X-​ray absorption spectroscopy and first principles calculations. J. Phys. Chem. A (2014), 118, 1568-1575.

Poineau, F.; Johnstone, E. V.; Sattelberger, A. P.; Czerwinski, K. R.

Characterization of TcCl4 and β-​TcCl3 by X-​ray absorption fine structure spectroscopy. J. Radioanal. Nucl. Ch. (2014), 299, 235-239.

Publications from 2013
Authors Reference
Johnstone, E. V.; Poineau, F.; Starkey, J.; Hartmann, T.; Forster, P. M.; Ma, L.; Hilgar, J.; Rodriguez, E. E.; Farmand, R.; Czerwinski, K. R.; Sattelberger, A. P.

Synthetic and coordination chemistry of the heavier trivalent technetium binary halides: uncovering technetium triiodide. Inorg. Chem. (2013), 52, 14309-14316.

Ferrier, M.; Poineau, F.; Jarvinen, G. D.; Czerwinski, K. R.

Chemical and electrochemical behavior of metallic technetium in acidic media J. Radioanal. Nucl. Ch. (2013), 298, 1809-1817.

Ferrier, M.; Kerlin, W. M.; Poineau, F.; Sattelberger, A. P.; Czerwinski, K. R.

Recent developments in the synthetic chemistry of technetium disulfide. Dalton Trans. (2013), 42, 15540-15543.

Mausolf, E.; Johnstone, E.; Poineau, F.; Nguyen, S.; Jones, S.; Hartmann, T.; Buck, E.; Czerwinski, K. R.

Formation of Tc metal in 12 M HCl using Zn as a reductant. J. Radioanal. Nucl. Ch. (2013), 298, 1315-1321.

Malliakas, C. D.; Poineau, F.; Johnstone, E. V.; Weck, P. F.; Kim, E.; Scott, B. L.; Forster, P. M.; Kanatzidis, M. G.; Czerwinski, K. R.; Sattelberger, A. P.

β-​Technetium dichloride: solid-​state modulated structure, electronic structure, and physical properties. J. Am. Chem. Soc. (2013), 135, 15955-15962.

Harder, S.; Naglav, D.; Ruspic, C.; Wickleder, C.; Adlung, M.; Hermes, W.; Eul, M.; P.; Rainer; Rego, D. B.; Poineau, F.; et al.

Physical properties of superbulky lanthanide metallocenes: synthesis and extraordinary luminescence of [Eu(II)​(CpBIG)​2] (CpBIG=(4-​nBu-​C6H4)​5-​cyclopenta-dienyl). Chem. - Eur. J. (2013), 19, 12272-12280.

Jarvinen, G. D.; Long, K. M.; Goff, G. S.; Runde, W. H.; Mausolf, E. J.; Czerwinski, K. R.; Poineau, F.; McAlister, D. R.; Horwitz, E. P.

Separation of pertechnetate from uranium in a simulated UREX processing solution using anion exchange extraction chromatography. Solvent Extr. Ion Exch. (2013), 31, 416-429.

Poineau, F.; Weck, P. F.; Burton-Pye, B. P.; Kim, E.; Francesconi, L. C.; Sattelberger, A. P.; German, K. E.; Czerwinski, K. R.

Diperoxo pertechnetic acid characterized by spectroscopic and quantum chemical studies. Eur. J. Inorg. Chem. (2013), 2013, 4595-4600.

Johnstone, E. V.; Grant, D. J.; Poineau, F.; Fox, L.; Forster, P. M.; Ma, L.; Gagliardi, L.; Czerwinski, K. R.; Sattelberger, A. P.

A trigonal-​prismatic hexanuclear technetium(II) bromide cluster: solid-​state synthesis and crystallographic and electronic structure. Inorg. Chem. (2013), 52, 5660-5662.

Poineau, F.; Weck, P. F.; Burton-Pye, B. P.; Denden, I.; Kim, E.; Kerlin, W.; German, K. E.; Fattahi, M.; Francesconi, L. C.; Sattelberger, A. P.; et al.

Reactivity of HTcO4 with methanol in sulfuric acid: Tc-​sulfate complexes revealed by XAFS spectroscopy and first principles calculations. Dalton Trans. (2013), 42, 4348-4352.

Poineau, F.; Burton-Pye, B. P.; Maruk, A.; Kirakosyan, G.; Denden, I.; Rego, D. B.; Johnstone, E. V.; Sattelberger, A. P.; Fattahi, M.; Francesconi, L. C.; et al.

On the nature of heptavalent technetium in concentrated nitric and perchloric acid. Inorg. Chim. Acta (2013), 398, 147-150.

Johnstone, E. V.; Weck, P. F.; Poineau, F.; Kim, E.; Forster, P. M.; Sattelberger, A. P.; Czerwinski, K. R.

X-​ray Crystallographic and first-​principles theoretical studies of K2[TcOCl5] and UV​/Vis investigation of the [TcOCl5]​2- and [TcOCl4]​- ions. Eur. J. Inorg. Chem. (2013), 2013, 1097-1104.

Kerlin, W. M.; Poineau, F.; Czerwinski, K. R.; Forster, P. M.; Sattelberger, A. P.

Hydrothermal synthesis and solid-​state structure of Tc2(​O2CCH3)​4Cl2. Polyhedron (2013), 58, 115-119.

Poineau, F.; Mausolf, E.; Jarvinen, G. D.; Sattelberger, A. P.; Czerwinski, K. R.

Technetium chemistry in the fuel cycle: combining basic and applied studies. Inorg. Chem. (2013), 52, 3573-3578.

Publications from 2012
Authors Reference
Poineau, F., Johnstone, E.V., Weck, P.F., Forster, P.M., Kim, E., Czerwinski, K.R., and Sattelberger, A.P. β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations. Inorg. Chem., 51(9), 4915-4917 (2012).
Poineau, F., Johnstone, P.F., Forster, P.M., Ma, L., Sattelberger, A.P., and Czerwinski, K.R. Probing the Presence of Multiple Metal−Metal Bonds in Technetium Chlorides by X‑ray Absorption Spectroscopy: Implications for Synthetic Chemistry, Inorg. Chem., 51, 9563-957- (2012).
Johnstone, E.V., Poineau, F., Forster, P.M., Ma, L., Hartmann, T., Cornelius, A., Antonio, D., Sattleberger, A.P, Czerwinski, K.R. Technetium tetrachloride revisited: A precursor to lower-valent binary technetium chlorides. Inorg. Chem., 51(15), 8462-8467 (2012).
Plaue, J.W., Klunder, G.L., Hutcheon, I.D., Czerwinski, K.R. Near infrared reflectance spectroscopy as a process signature in uranium oxides, J. Radioanal. Nucl. Chem., 1-5, 2012. 
Poineau, F., Mausolf, E., Jarvinen, G.D., Sattelberger, A.P., and Czerwinski, K.R. Technetium Chemistry in the Fuel Cycle: Combining Basic and Applied Studies, Inorg. Chem., 2012
Kerlin, William, Poineau, F., Czerwinski, K.R., Forster, P.M., and Sattelberger, A.P. Hydrothermal synthesis and solid-state structure of Tc2(m-O2CCH3)4Cl2, Polyhedron, (2012)
Silva, G. W. Chinthaka, Weck, Philippe F., Kim, Eunja, Yeamans, Charles B., Cerefice, Gary S., Sattelberger, Alfred P., Czerwinski, Kenneth R. Crystal and Electronic Structures of Neptunium Nitrides Synthesized Using a Fluoride Route, J. Amer. Chem. Soc. 134(6), 3111-3119 (2012).
Holliday, Kiel; Hartmann, Thomas; Cerefice, Gary; Czerwinski, Ken Dissolution behavior of plutonium containing zirconia-magnesia ceramics, J. Nucl. Mat. 422(1-3), 109-115 (2012)
Frederic, F., Forster P.M., Todorova T.K., Gagliardi L., Sattelberger A.P., Czerwinski K.R. Multi-configurational quantum chemical studies of the Tc2X8n− (X = Cl, Br; n = 2, 3) anions. Crystallographic structure of octabromoditechnetate(3−). Dalton Trans. 41(10), 2869-72 (2012).
Silva, G. W. Chinthaka, Yeamans, Charles B., Weck, Philippe F., Hunn, John D., Cerefice, Gary S., Sattelberger, Alfred P., and Czerwinski, Kenneth R. Synthesis and Characterization of Th2N(NH) Isomorphous to Th2N3. Inorg. Chem. 51, 3332-3340 (2012).
Poineau, F., Johnstone, E.V., Weck, P.F., Kim, E., Conradson, S.D., Sattelberger, A.P., and Czerwinski, K.R. On the Structure of β-Molybdenum Dichloride. Inorg. Chem., 51(9), 4965-4971 (2012).
Poineau, F., Yeamans, C.B., Silva, G.W.C., Cerefice, G.S., Sattelberger, A.P., and Czerwinski, K.R. X-ray absorption fine structure spectroscopic study of uranium nitrides. J. Radioanal. Nucl. Chem., 292, 989-994 (2012).
Mausolf, E., Droessler, J., Poineau, F., Hartmann, T., and Czerwinski, K. Tetraphenylpyridinium Pertechnetate: a Promising Salt for the Immobilization of Technetium, Radiochim. Acta., 100, 325-328 (2012).
Ferrier, M., Weck, P.F., Poineau, F., Kim, E., Stebbins, A., Ma, L., Sattelberger, A.P., Czerwinski, K.R. First Evidence for the Formation of Technetium Oxosulfide Complexes: Synthesis, Structure and Characterization. Dalton Trans., 41(20), 6291-6298 (2012).
Publications from 2011
Authors Reference
Holliday, K., Hartmann, T., Cerefice, G., Czerwinski, K. Environmental behavior of ZrO2-MgO ceramics containing UO2, Radiochim. Acta 99(12), 799-806 (2011).
Silva, G.W.C., Hunn, J.D., Yeamans, C., Cerefice, G.S., Czerwinski, K.R. Fluoride-Conversion Synthesis of Homogeneous Actinide Oxide Solid Solutions, Inorg. Chem., 50, 11004–11010 (2011).
Poineau, F., Malliakas, C.D., Weck, P.F., Scott, B.L., Johnstone, E.V., Forster, P.M., Kim, E., Kanatzidis, M. G., Czerwinski, K.R., Sattelberger, A.P. Technetium Dichloride: A New Binary Halide Containing Metal-Metal Multiple Bonds, JACS, 133(23), 8814-8817 (2011).
Holliday, K. Smith, N., Hartmann, T., Cerefice, G., Czerwinski, K. Acidic dissolution behavior of U containing ZrO2-MgO ceramics, Annals of Nuclear Energy 38(11), 2404-2409 (2011).
Weck, P.F., Gong, C.M.S., Kim, E., Thuery, P., Czerwinski, K.R. One-dimensional uranium-organic coordination polymers: crystal and electronic structures of uranyl-diacetohydroxamate. Dalton Trans., 40(22), 6007-6011 (2011).
Weck, P.F., Kim, E., Czerwinski, K.R. Interplay between structure, stoichiometry and properties of technetium nitrides.  Dalton Trans., 40(25), 6738-6744 (2011).
Weck, P.F., Sergeeva, A.P., Kim, E., Boldyrev, A.I., Czerwinski, K.R. Chemical Bonding and Aromaticity in Trinuclear Transition-Metal Halide Clusters. Inorg. Chem., 50(3), 1039-1046 (2011).
McGregor, D., Burton-Pye, B.P., Howell, R.C., Mbomekalle, I.M., Lukens, W.W., Bian, F., Mausolf, E., Poineau, F., Czerwinski, K.R., Francesconi, L.C. Synthesis, Structure Elucidation, and Redox Properties of 99Tc Complexes of Lacunary Wells-Dawson Polyoxometalates: Insights into Molecular 99Tc-Metal Oxide Interactions. Inorg. Chem., 50(5), 1670-1681 (2011). 
Mausolf, E., Poineau, F., Hartmann, T., Droessler, J., Czerwinski, K. Characterization of electrodeposited technetium on gold foil. J. Electrochem. Soc., 158(3), E32-E35 (2011)
Hartmann, T., Alaniz, A., Poineau, F., Weck, P. F., Valdez, J. A., Tang, M., Jarvinen, G. D., Czerwinski, K. R., Sickafus, K. E.:  Structure studies on lanthanide technetium pyrochlores as prospective host phases to immobilize 99-technetium and fission lanthanides from effluents of reprocessed used nuclear fuels. J. Nucl. Mat., 411(1-3), 60-71 (2011).
Mausolf, E., Poineau, F., Droessler, J., Czerwinski, K.R.:  Spectroscopic and structural characterization of reduced technetium species in acetate media. J. Radio. Nucl. Chem., 288(3), 723-728 (2011).
O'Dou, T.J., Bertoia, J., Czerwinski, K.R. Decontamination of a Technetium Contaminated Fume Hood in a Research Laboratory. Health Phys., 101(2), 124-130 (2011)
Publications from 2010
Authors Reference
Poineau, F.; Johnstone, E.; Weck, P.; Kim, E.; Forster, P.; Scott, B.; Sattelberger, A.; Czerwinski, K.:  Synthesis and Structure of Technetium Trichloride, J. Amer. Chem. Soc., 132, 15864-15865 (2010).
Warburton, J., Smith, N., and Czerwinski, K.: Method for Online Process Monitoring for Use in Solvent Extraction and Actinide Separations, Sep. Sci. Tech., 45(12-13), 1763-1768 (2010).
Holliday, K., Hartmann, T., Mulcahy, S.R., and Czerwinski, K.:  Synthesis and Characterization Of Zirconia-Magnesia Inert Matrix Fuel: Plutonium Studies, J. Nucl. Mat., 402(1), 81-86 (2010).
Cho, H., de Jong, W.A., Sattelberger, A.P., Poineau, F., Czerwinski, K.R.:  Comprehensive Solid-State NMR Characterization of Electronic Structure in Ditechnetium Heptoxide. J. Amer. Chem. Soc., 132(38), 13138-13140 (2010).
Poineau, F., Weck, P. F., German, K., Maruk, A., Kirakosyan, G., Lukens, W., Rego, D.B., Sattelberger, A.P., Czerwinski, K.R.:  Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies. Dalton Trans. 39(37), 8616-8619 (2010). 
Burns, P. C., Ikeda, Y., Czerwinski, K.:  Advances in actinide solid-state and coordination chemistry. MRS Bulletin 35(11), 868-876, (2010). 
Tang, M, K.S. Holliday, K.S., Valdez, J.A., Uberuaga, B.P., Dickerson, P.O., Dickerson, R.M., Wang, Y., Czerwinski, K.R., Sickafus, K.E.:  Microstructural evolution in irradiated uranium-bearing delta-phase oxides A6U1O12 (A = Y, Gd, Ho, Yb, and Lu), J. Nucl. Mat. 407, 44-47 (2010).
Briggs, B.N., McMillin, D.R., Todorova, T.K., Gagliardi, L., Poineau, F., Czerwinski, K.R., and Sattelberge, A.P.:  First Emission Studies of Tc2X82- Systems (X = Cl, Br), Dalton Trans., 39(47), 11322-11324 (2010).
Weck, P.F., Kim, E., Poineau, F., Rodriguez, E.E., Sattelberger, A.P., and Czerwinski, K.R.:  Structural and electronic trends in rare-earth technetate pyrochlores. Dalton Trans., 39, 7207-7210 (2010).
Poineau, F., Forster, P. M., Todorova, T. K., Gagliardi, L., Sattelberger, A. P., Czerwinski, K. R:  Structural, Spectroscopic, and Multiconfigurational Quantum Chemical Investigations of the Electron-Rich Metal-Metal Triple-Bonded Tc2X4(PMe3)4 (X = Cl, Br) Complexes. Inorg, Chem., 49(14), 6646-6654 (2010).
Philippe F. Weck, Eunja Kim, Kenneth R. Czerwinski, and David Tománek: Structural and magnetic properties of Tcn@C60 endohedral metalofullerenes: First-principles predictions: Phy. Rev. B., 81, 125448 (2010).
Douglas E. Burkes, Ramprashad Prabhakaran, Thomas Hartmann, Jan-Fong Juea, Francine J. Rice: Properties of DU–10 wt% Mo alloys subjected to various post-rolling heat treatments., Nucl. Eng. Des., 240, 1332-1339 (2010).
Douglas E. Burkes, J. Rory Kennedy, Thomas Hartmann, Cynthia A. Papesch, Dennis D. Keiser Jr.: Phase characteristics of a number of U–Pu–Am–Np–Zr metallic alloys for use as fast reactor fuels. J. Nucl. Mat., 396, 49-56 (2010).
M. Tang, K.S.Holliday, C.Jiang, J.A.Valdez, B.P.Uberuaga, P.O.Dickerson, R.M.Dickerson, Y. Wang, K.R.Czerwinski, K.E.Sickafus: Order-to disorder phase transformation in ion irradiated uranium-bearing delta-phase oxides RE6U1O12 (RE=Y, Gd, Ho, Yb, and Lu), J. Sol. State. Chem.183 844-848 (2010).
Yu. Ts. Oganessian, F. Sh. Abdullin, P. D. Bailey, D. E. Benker, M. E. Bennett, et. al. Synthesis of a New Element with Atomic Number Z = 117, Phys. Rev. Lett., 104, 142502 (2010).
Weck, Philippe F.; Kim, Eunja; Czerwinski, Kenneth R. First-principles study of the hexahalogenotechnetate(IV) ions TcX62- [X = Cl, Br]. Chemical Physics Letters  487(4-6), 190-193 (2010)
Poineau, Frederic, Hartmann, Thomas, Weck, Philippe F., Kim, Eunja, Silva, G. W. Chinthaka, Jarvinen, Gordon D., Czerwinski, Kenneth R.:  Structural Studies of Technetium-Zirconium Alloys by X-ray Diffraction, High-Resolution Electron Microscopy, and First-Principles Calculations. Inorg.  Chem. 49(4), 1433-1438 (2010).
Weck, Philippe F.; Kim, Eunja; Masci, Bernardo; Thuery, Pierre; Czerwinski, Kenneth R. Density Functional Analysis of the Trigonal Uranyl Equatorial Coordination in Hexahomotrioxacalix[3]arene-based Macrocyclic Complexes. Inorg. Chem. 49(4), 1465-1470 (2010).
Publications from 2009
Authors Reference
Schutzer, Steven E., Keim, Paul, Czerwinski, Ken, Budowle, Bruce Use of Forensic Methods Under Exigent Circumstances Without Full Validation, Science Translational Medicine, 1(8), 1-3 (2009)
Weck, Philippe F.; Kim, Eunja; Poineau, Frederic; Rodriguez, Efrain E.; Sattelberger, Alfred P.; Czerwinski, Kenneth R.: Technetium(IV) Halides Predicted from First-Principles, Inorg. Chem.  48(14), 6555-6558 (2009).
Poineau, Frederic; Gagliardi, Laura; Forster, Paul M.; Sattelberger, Alfred P.; Czerwinski, Kenneth R.: Crystal structure of octabromoditechnetate(III) and
a multi-configurational quantum chemical study of the dd* transition in quadruply bonded [M2X8]2-dimers (M = Tc, Re; X = Cl, Br), Dalton Transactions, 30, 5954-5959 (2009)
Poineau, F., Hartmann, T., Jarvinen, G., and Czerwinski, K.R.: Preparation of technetium metal by thermal treatment under Argon/H2O, J. Radioanal. Nucl. Chem., 279(1), 43-48 (2009).
Poineau, F., Rodriguez, E.E., Forster, P.M. Sattelberger, A.P., Cheetham, A.K., Czerwinski, K.R.:

Preparation of the Binary Technetium Bromides: TcBr3 and TcBr4JACS, 131(3), 910-911 (2009).

Poineau, F., Weck, P.F., Forster, P.M., Sattelberger, A.P.and Czerwinski, K.R.:  Synthesis, structure, and first-principles calculations of [TcBr2(PMe3)4] and[Tc2Br4(PMe3)4] complexes, Dalton Trans., 10338-10342 (2009).
Poineau, F.; Rodriguez, E. E.; Weck, P. F.; Sattelberger, A. P.; Forster, P.; Hartmann, T.; Mausolf, E.; Silva, G. W. C.; Jarvinen, G. D.; Cheetham, A. K.; Czerwinski, Kenneth R..:  Review of technetium chemistry research conducted at the University of Nevada Las Vegas. J. Radioanal. Nucl. Chem. 282(2), 605-609 (2009). 
Weck, P.F.; Kim, E.; Poineau, F.; Czerwinski, K.R.:  Structural evolution and properties of subnanometer Tcn (n = 2-15) clusters. Physical Chemistry Chemical Physics, 11(43), 10003-10008 (2009).
Silva, G. W. C.; Yeamans, C.B.; Sattelberger, A.P.; Hartmann, T.; Cerefice, G.S.; Czerwinski, K.R.:  Reaction Sequence and Kinetics of Uranium Nitride Decomposition.  Inorganic Chemistry, 48(22), 10635-10642 (2009).
Shin, J.; Bertoia, J.; Czerwinski, K.R.; Bae, C.:  A new homogeneous polymer support based on syndiotactic polystyrene and its application in palladium-catalyzed Suzuki-Miyaura cross-coupling reactions. Green Chemistry 11(10), 1576-1580 (2009).
Xu, P.; Holliday, K.; Czerwinski, K. R.; Nino, J. C.:   Dissolution behavior of MgO-pyrochlore composites in acidic solutions. J. Nucl. Mat. 394(1), 39-45 (2009).
Holliday, K.; Hartmann, T.; Poineau, F., Kennedy, J.R., and Czerwinski, K.:  Synthesis and characterization of zirconia–magnesia inert matrix fuel: Uranium homolog studies, J. Nucl. Mat., 393, 224-229 (2009).
Holliday, K.; Hartmann, T.; Czerwinski, K.:   Synthesis and characterization of zirconia-magnesia inert matrix fuel: Ce homolog studies. J. Nucl. Mat. 392(3), 487-493 (2009).
Silva, G. W. Chinthaka; Yeamans, Charles B.; Cerefice, Gary S.; Sattelberger, Alfred P.; Czerwinski, Kenneth R.:  Synthesis and Nanoscale Characterization of (NH4)4ThF8 and ThNF. Inorg. Chem. 48(13), 5736-5746 (2009).
Tang, M.; Holliday, K. S.; Valdez, J. A.; Uberuaga, B. P.; Dickerson, P. O.; Dickerson, R. M.; Wang, Y.; Czerwinski, K. R.; Sickafus, K. E.:  Radiation damage effects in the uranium-bearing d-phase oxide Y6U1O12. J. Nucl. Mat., 389(3), 497-499 (2009).   
Publications from 2008
G. W. Chinthaka Silva, Frederic Poineau, Longzhou Ma, and Kenneth R. Czerwinski
Application of Electron Microscopy in the Observation of Technetium and Technetium Dioxide Nanostructures, Inorg. Chem., 47(24), 11738-11744 (2008).
G. W. Chinthaka Silva, Oliver Hemmers, Ken R. Czerwinski, and Dennis W. Lindle
Investigation of Nanostructure and Thermal Behavior of
Zinc-Substituted Fluorapatite, Inorg. Chem., 47, 7757-7767 (2008).
Cynthia-May S. Gong, Wayne W. Lukens, Frederic Poineau, and Kenneth R. Czerwinski
Reduction of Pertechnetate by Acetohydroxamic Acid: Formation of [TcII(NO)(AHA)2(H2O)]+ and Implications for the UREX Process, Inorg. Chem., 47, 6674-6680 (2008).
G. W. Chinthaka Silva, Charles B. Yeamans, Longzhou Ma, Gary S. Cerefice,Kenneth R. Czerwinski, and Alfred P. Sattelberger
Microscopic Characterization of Uranium Nitrides Synthesized by Oxidative Ammonolysis of Uranium Tetrafluoride, Chem. Mater., 20, 3076-3084 (2008).
Poineau, Frederic; Sattelberger, Alfred P.; Conradson, Steven D.; Czerwinski, Kenneth R:
Octachloro- and Octabromoditechnetate(III) and Their Rhenium(III) Congeners, Inorganic Chemistry, 47(6), 1991-1999 (2008).
Radiochim. Acta
February, 2008
Uranium/technetium separation for the UREX process– synthesis and characterization of solid reprocessing forms
Inorganic Chemistry
February, 2008
Preparation and Crystal Structures of Bismuth Technetates: A New Metal Oxide System
XAFS spectroscopic study of Tc2(O2CCH3) 4 X2 (X = Cl, Br)
Physical Review Letters
January 18, 2008
Lightest Isotope of Bh Produced via the 209Bi 52Cr; 260Bh Reaction


Synthesis and Properties of Metallic Technetium and Technetium-Zirconium Alloys as Transmutation Target and Radioactive waste storage form in the UREX+1 Process
Publications from 2007
First-principles study of single-crystal uranium mono- and dinitride
Oxidative ammonolysis of uranium(IV) fluorides to uranium(VI) nitride
Structural Studies of TcO2 by Neutron Powder Diffraction and First-Principles Calculations
Radiochimica Acta
February, 2007
First-principles study of single-crystal uranium mono- and dinitride
Publications from 2006
Complexation of uranium(VI) with the siderophore desferrioxamine B
Actinide Third Phase Formation in 1.1M TBP/Nitric Acid/Alkane Diluent Systems
Plutonium Third Phase Formation in the 30% TBP/Nitric Acid/Hydrogenated Polypropylene Tetramer System
Comparison of Uranyl Third-Phase Formation in 30% TBP-Nitric Acid in Dodecane and HPT using UV-Visible Spectroscopy
Small-Angle Neutron Scattering Study of Plutonium Third Phase Formation in 30% TBP/HNO3/Alkane Diluent Systems
  last update: Friday 04-Nov-2016